Journal
ORGANIC LETTERS
Volume 21, Issue 6, Pages 1853-1856Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00447
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- JSPS KAKENHI
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Chiral binaphthyl-strapped Zn(II) porphyrins with triazolium halide units were synthesized as bifunctional catalysts for kinetic resolution of epoxides with CO2. Several catalysts were screened by changing the linker length and nucleophilic counteranions, and the optimized catalyst accelerated the enantioselective reaction at ambient temperature to produce optically active cyclic carbonates and epoxides.
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