Journal
ORGANIC LETTERS
Volume 21, Issue 6, Pages 1708-1712Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00271
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Funding
- NIH [CA-19033, GM-29028]
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Visible-light-induced generation of dithianyl and dioxolanyl radicals via selective hydrogen atom transfer (HAT) has been achieved. This radical relay tactic enables remote C(sp(3))-H functionalization to permit rapid access to polyol and spiroketal segments, and in turn has been exploited as a key synthetic construct in the total synthesis of the danshenspiroketallactones. The conformational stability of the danshenspiroketallactones has also been defined via experiments and DFT calculations.
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