Journal
ORGANIC LETTERS
Volume 21, Issue 6, Pages 1749-1754Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00315
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Funding
- NNSFC [21572238, 21772208, 21633013, 21822303, 21772020]
- NSFC of Jiangsu Province [BK20161260]
- Hundred-Talented Program of the Chinese Academy of Sciences, LICP
- Chongqing University
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A Pd-catalyzed enantioselective C-H carbonylation by desymmetrization was developed with commercially available L-pyroglutamic acid as chiral ligand. Isoquinolinones were successfully obtained with good yields and high enantioselectivities. Mechanistic studies and DFT calculations provided a reasonable reaction pathway.
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