Journal
ORGANIC LETTERS
Volume 21, Issue 7, Pages 2430-2435Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00729
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Funding
- MINECO of Spain [CTQ2015-70795-P, BES-2013-066564]
- Catalan DIUE of the Generalitat de Catalunya [2017 SGR 264]
- ICREA-Academia Award
- MECD of Spain [FPU16/04231]
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Enantioselective epoxidation of beta,beta-disubstituted enamides with aqueous hydrogen peroxide and a novel manganese catalyst is described. Epoxidation is stereospecific and proceeds fast under mild conditions. Amides are disclosed as key functional groups to enable high enantioselectivity.
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