Journal
ORGANIC LETTERS
Volume 21, Issue 5, Pages 1301-1305Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b04081
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Funding
- Recruitment Program of Global Experts
- Fundamental Research Funds for the Central Universities [lzujbky-2018-62]
- International Joint Research Centre for Green Catalysis and Synthesis
- Gansu Provincial Sci. & Tech. Department [2016B01017, 18JR3RA284, 18JR4RA003]
- Lanzhou University
- E.B. Eddy Endowment Fund
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Photoinduced transition-metal- and photosensitizer-free cross coupling of aryl halides (including Ar-Cl, Ar-Br, and Ar-I) with H-phosphonates (including dialkyl phosphonates and diarylphosphine oxides) is reported. Various functional groups were tolerated, including ester, methoxy, dimethoxy, alkyl, phenyl, trifluoromethyl, and heterocyclic compounds. This simple and green strategy provides a practical pathway to synthesize arylphosphine oxides.
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