Journal
ORGANIC LETTERS
Volume 21, Issue 3, Pages 802-806Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b04064
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Funding
- Ministere de la Recherche et de l'Enseignement Superieur
- CNRS
- Region Bretagne [Balaton PHC (38522ZH)]
- French National Research Agency [ANR-16-CE05-0003-01, ANR-17-CE09-0020, OTKA NN 113772]
- COST [CM10302, PICS SmartPAH (08062)]
- Agence Nationale de la Recherche (ANR) [ANR-16-CE05-0003, ANR-17-CE09-0020] Funding Source: Agence Nationale de la Recherche (ANR)
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In this letter, we present the synthesis of a new family of pi-extended dithieno[b,f]phosphepines. The Pd-catalyzed direct arylation allows the introduction of various substituents, which tune the absorption/emission in the visible range as well as the redox properties. All those modifications were rationalized through DFT calculations. The physical properties of ambipolar phosphepine with diphenylamino substituents inspired us to use it as a semiconductor in p-type organic field-effect transistors (OFETs).
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