Journal
ORGANIC LETTERS
Volume 21, Issue 3, Pages 797-801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b04059
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Funding
- National Natural Science Foundation of China [21772134, 21472127]
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A novel naphthotetraindole (NTI) core was synthesized in two steps via the McMurry reaction and a [Cu]/[Ag]-promoted intramolecular dehydrogenative homocoupling reaction. NTI shows a unique X-shaped double-helical structure as determined by single-crystal X-ray diffraction analysis. The hole-transport mobility of the bare NTI core was measured to be 2.3 x 10(-5) cm(2) V-1 s(-1), which is comparable with the commonly used Spiro-OMeTAD.
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