4.8 Article

Palladium-Catalyzed Oxidative Allylation of Sulfoxonium Ylides: Regioselective Synthesis of Conjugated Dienones

Journal

ORGANIC LETTERS
Volume 21, Issue 4, Pages 872-875

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03606

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Funding

  1. National Key Research and Development Program of China [2016YFA0602900]
  2. National Natural Science Foundation of China [21420102003]
  3. Guangdong Province Science Foundation [2017B090903003]

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The first examples of palladium-catalyzed allylic C-H oxidative allylation of sulfoxonium ylides to afford the corresponding conjugated dienones with moderate to good yields have been established. The features of this novel conversion include mild reaction conditions, wide substrate scope, and excellent regioselectivity.

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