Journal
ANALYTICAL CHEMISTRY
Volume 88, Issue 16, Pages 7885-7889Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.6b02216
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Funding
- National Natural Science Foundation of China [21575137]
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It is highly attractive to construct a natural enzyme-free electrode for sensitive and selective detection of glucose. In this Letter, we report that a Ni2P nanoarray on conductive carbon cloth (Ni2P NA/CC) behaves as an efficient three-dimensional catalyst electrode for glucose electooxidation under alkaline conditions. Electrochemical measurements demonstrate that the Ni2P NA/CC, when used as a nonenzymatic glucose sensor, offers superior analytical performances with a short response time of 5 s, a wide detection range of 1 mu M to 3 mM, a low detection limit of 0.18 mu M (S/N = 3), a response sensitivity of 7792 mu A mM(-1) cm(-2), and satiSfactory selectivity) specificity, and reproducibility. Moreover, it can also be used for glucose detection in human blood serum, promising its application toward determination of glucose in real samples.
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