Journal
MICROCHIMICA ACTA
Volume 186, Issue 3, Pages -Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-019-3254-7
Keywords
Simultaneous detection; Herbicides; Molecular imprint; Food safety; AuNPs; Portable Raman spectrometer; Matrix interference; Multi-residues; Grain
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Funding
- National Natural Science Foundation of China [31471654, 31772071, 31501571]
- China Agriculture Research System [CARS-05-05A-03]
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A class-specific molecular imprinted polymer (MIP) is described for simultaneous recognition of prometryn and simetryn prior to their determination via a fingerprint signal (at 974cm(-1) and 1074cm(-1)) in the surface enhanced Raman scattering (SERS) spectra that were acquired in the presence of gold nanoparticles. The imprinted nanoparticles were applied to the analysis of rice and wheat samples spiked with both herbicides. The method has fairly good recoveries (72.7-90.9%) with a relative standard deviation of 1.7-7.8%, and a 20gkg(-1) limit of detection. The imprint factors (compared to non-imprinted polymers) are 5.3 for prometryn and 4.2 for simetryn (both at 10gmL(-1) of the initial solution).
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