Applications of three-dimensional graphenes for preconcentration, extraction, and sorption of chemical species: a review

This review (with 115 refs) summarizes applications of 3-dimensional graphene (3DGs) and its derivatives in the fields of preconcentration, extraction, and sorption. Following an introduction into the field (including a definition of the materials treated here), the properties and synthetic strategies for 3DGs are described. The next section covers applications of 3DG-based adsorbents in solid phase extraction of organic species including drugs, phthalate esters, chlorophenols, aflatoxins, insecticides, and pesticides. Another section treats applications of 3DGs in solid phase microextraction of species such as polycyclic aromatic hydrocarbons, alcohols, and pesticides. We also describe how the efficiency of assays may be improved by using these materials as a sorbent. A final section covers conclusions and perspectives.