4.7 Article

Evaluation of a reconfigurable portable instrument for copper determination based on luminescent carbon dots

Journal

ANALYTICAL AND BIOANALYTICAL CHEMISTRY
Volume 408, Issue 11, Pages 3013-3020

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00216-016-9349-7

Keywords

Carbon dots; Luminescence; Reconfigurable electronics; FPAA; Copper determination

Funding

  1. Spanish MINECO [CTQ2013-44545-R]
  2. Junta de Andalucia [P10-FQM-5974]
  3. Fortalecimiento de Grupos program
  4. Reincorporacion de Doctores program
  5. ERDF

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A portable reconfigurable platform for copper (Cu(II)) determination based on luminescent carbon dot (Cdots) quenching is described. The electronic setup consists of a light-emitting diode (LED) as the carbon dot optical exciter and a photodiode as a light-to-current converter integrated in the same instrument. Moreover, the overall analog conditioning is simply performed with one integrated solution, a field-programmable analog array (FPAA), which makes it possible to reconfigure the filter and gain stages in real time. This feature provides adaptability to use the platform as an analytical probe for carbon dots coming from different batches with some variations in luminescence characteristics. The calibration functions obtained that fit a modified Stern-Volmer equation were obtained using luminescence signals from Cdots quenching by Cu(II). The analytical applicability of the reconfigurable portable instrument for Cu(II) using Cdots has been successfully demonstrated in tap water analysis.

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