4.6 Article

Facile synthesis of ZnO nanoflowers/reduced graphene oxide nanocomposite using zinc hexacyanoferrate for supercapacitor applications

Journal

MATERIALS LETTERS
Volume 236, Issue -, Pages 424-427

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2018.10.111

Keywords

Zinc oxide; Nanoflowers; Graphene; Nanocomposite; Energy storage; Supercapacitor

Funding

  1. Science & Engineering Research Board, Department of Science and Technology (DST-SERB), India [EMR/2016/006807, IF131153]
  2. DST [IF131153]

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We demonstrated a facile and scalable synthesis of crystalline hexagonal ZnO nanoflowers/reduced graphene oxide nanocomposite (ZnO-NFs/RGO NCs) via direct chemical decomposition of zinc hexacyanoferrate (ZnHCF) over reduced graphene oxide (RGO) nanosheets. The phase formation and degree of functionalization of as-synthesized ZnO-NFs/RGO NCs was confirmed from XRD and FT-IR spectroscopic analysis, respectively. The hierarchical ZnO nanoflowers consist of 2D nanosheets wrapped with RGO nanosheets was confirmed from FE-SEM and HR-TEM images. The synthesized ZnO-NFs/RGO NCs exhibits a high specific capacitance of 203 F g(-1) at the current density of 1 Ag-1 with good rate performance and also showed an excellent electrochemical stability of 98% for 10,000 cycles at high current density of 20 A g(-1). (C) 2018 Elsevier B.V. All rights reserved.

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