4.6 Article

Solvothermal synthesis of mesoporous NiCoP for high performance electrochemical supercapacitors

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 224, Issue -, Pages 124-128

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2018.12.011

Keywords

Supercapacitors; Metal phosphides; Mesoporous; NiCoP

Funding

  1. University Grants Commission (UGC), Government of India [F.4-2/2006(BSR)/CH/14-15/0133]

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Mesoporous NiCoP is synthesized by a one pot solvothermal route and is studied for its morphology, structure, composition. As charge storage in electrochemical supercapacitors is a surface phenomenon, its electrochemical characterizations will be of high interest. The specific capacitance of the as prepared NiCoP is 188 C/g (418 F/g) at 8 A/g and 140 C/g (311 F/g) at a higher specific current density of 20 A/g in 3 M KOH. Interestingly, capacity retention after 5000 cycles at high current of 20 A/g is 97%. Mesoporous NiCoP is a promising electrode material, which exhibits high specific capacity and very long cycle life.

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