Journal
MATERIALS CHEMISTRY AND PHYSICS
Volume 226, Issue -, Pages 344-349Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2019.01.053
Keywords
Metal-matrix composites (MMCs); Multi-walled carbon nanotubes (MWCNTs); Interface; Mechanical properties; Fracture mechanism
Categories
Funding
- National Key R&D program of China [2017YFB0703103]
- National Natural Science Foundation of China (NSFC) [U1537201]
- China Postdoctoral Science Foundation [2017M620114]
- Fundamental Research Funds for the Central Universities [HIT.NSRIF.201801]
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Homogeneous distribution of multi-walled carbon nanotubes (MWCNTs) in aluminum matrix composites and optimization of the MWCNTs-aluminum interfacial strength are challenging for MWCNTs/Al metal-matrix composites (MMCs). Here, in order to improve the wettability and the interfacial bonding between MWCNTs and aluminum matrix alloy, a uniform nickel layer was created on MWCNTs by electroless plating. Hybrid preforms comprising of aluminum borate whisker (ABOw) and MWCNTs with/without nickel coating were prepared. It was found that the presence of ABOw and nickel coating ensured the homogeneous distribution of MWCNTs in composites. The presence of the nickel coating on MWCNTs also helps in decreasing the porosity of composite prepared by squeeze casting technique. Compared with ABOw/2024Al and ABOw + MWCNTs/2024Al composites, improvements in elongation and hardness were obtained in the ABOw + MWCNTs(Ni)/2024Al composite, which may be attributed to the reduced porosity, increased interfacial bonding strength and the crack deflection induced by dispersed MWCNTs. However, the addition of MWCNTs did not change the main fracture mechanism: ABOw break and ABOw-aluminum interfacial de-bonding dominated the fracture process in ABOw and MWCNTs(Ni) reinforced composites.
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