Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 13, Pages 5402-5408Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b00053
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Funding
- National Natural Science Foundation of China (NSFC) [21672221, 21734009, 21790361, 91427303]
- 973 Program [2015CB856502]
- Youth Innovation Promotion Association of Chinese Academy of Sciences
- National Basic Research Program of China [2015CB856500]
- Qjan Ren Scholar Program of China
- Synergetic Innovation Center of Chemical Science and Engineering (Tianjin)
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Despite the great advances in the synthesis of diverse nonplanar graphenoids, investigations into the relationship between structural features and intermolecular interactions still present significant challenges. Herein, the novel nonplanar graphenoid structure, corannurylene pentapetalae (CRP), obtained via bottom-up syntheses of hybridization between perylene diimide (PDI) planar fragments and a corannulene curved core, is presented. Single crystal studies reveal a D-5-symmetric as well as a C-2-symmetric graphenoid corannurylene pentapetalae. The D-5-symmetric structure has a unique honeycomb lattice with two chiral honeycomb layers alternately stacked, whereas the C-2-symmetric CRP forms dimer units via pi-pi stacking. Transistor devices demonstrate that, without any pi-pi stacking, the honeycomb lattice of the D s symmetric CRP has the potential to also facilitate electron transport.
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