Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 6, Pages 2263-2267Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b00129
Keywords
-
Categories
Funding
- JSPS KAKENHI from MEXT (Japan) [JP15H03777, JP15K13640]
- Collaborative Research Program of the Institute for Chemical Research, Kyoto University
- DAIKO FOUNDATION
- JURC
- IRCCS
- KURCA (Kyoto University)
- [JP16J05501]
Ask authors/readers for more resources
The first examples of stable, crystalline, and air-sensitive 1,4-digermabenzenes were isolated. These species photochemically isomerize into the corresponding air-stable digerma-Dewar-benzenes. More importantly, alkyl-substituted Dewar-type-1,4-digermabenzenes can be considered as reversible air-stable activators for small molecules such as dihydrogen, carbon dioxide, and acetylene at room temperature. The regeneration of these activators can be accomplished via a thermal retro-isomerization that affords the corresponding 1,4-digermabenzenes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available