Journal
JOURNAL OF POWER SOURCES
Volume 412, Issue -, Pages 374-383Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2018.11.052
Keywords
Supercapacitors; Hybrid material; AC line filter; Energy storage; Internet of things
Funding
- EU Horizon 2020 research and innovation program Smart-MEMPHIS project [644378]
- Vinnova UDI project Energy Harvesting Toolkit
- Swedish Energy Agency
- Swedish Foundation for Strategic Research [SE13-0061, GMT14-0045]
- Production Area of Advance at Chalmers University of Technology, Sweden
- EU Horizon 2020 project Smartherm
- Ministry of Science and Technology of China [2017YFB040600]
- Shanghai Municipal Education Commission (Shanghai University High Education Peak Discipline Program)
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With the establishment of the internet of things (IoT) and the rapid development of advanced microsystems, there is a growing demand to develop electrochemical capacitors (ECs) to replace bulky electrolytic capacitors on circuit boards for AC line filtering, and as a storage unit in energy autonomous systems. For this purpose, ECs must be capable of handling sufficiently high signal frequencies, display minimum energy loss through self-discharge and leakage current as well as maintaining an adequate capacitance. Here, we demonstrate ECs based on mechanically flexible, covalently bonded graphite/vertically aligned carbon nanotubes (graphite/VACNTs) hybrid materials. The ECs employing a KOH electrolyte exhibit a phase angle of -84.8 degrees, an areal capacitance of 1.38 mF cm(-2) and a volumetric capacitance (device level) of 345 mF cm(-3) at 120 Hz, which is among the highest values for carbon based high frequency ECs. Additionally, the performance as a storage EC for miniaturized systems is evaluated. We demonstrate capacitive charging/discharging at mu A current with a gel electrolyte, and sub-mu A leakage current reached within 50 s, and 100 nA level equilibrium leakage within 100 sat 2.0 V floating with an ionic liquid electrolyte.
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