Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 57, Issue 8, Pages 869-877Publisher
WILEY
DOI: 10.1002/pola.29337
Keywords
cross-linking-induced thermoresponse; hydrogel; light emission; self-healing; TPE
Categories
Funding
- National Natural Science Foundation of China [81502477]
- Natural Science Foundation of Hebei Province [B2018201140]
- Department of Education, Hebei Province [QN2017014]
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Development of self-healing hydrogels with thermoresponse is very important for artificial smart materials. In this article, the self-healing hydrogels with reversible thermoresponses were designed through across-linking-induced thermoresponse (CIT) mechanism. The hydrogels were prepared from ketone group containing copolymer bearing tetraphenyl ethylene (TPE) and cross-linked by naphthalene containing acylhydrazide cross-linker. The mechanical property, light emission, self-healing, and thermo-response of the hydrogels were investigated intensively. With regulation of the copolymer composition, the hydrogels showed thermoresponse with the LCST varied from above to below body temperature. At the same time, the hydrogels showed self-healing property based on the reversible characteristic of the acylhydrazone bond. The hydrogel also showed temperature-regulated light emission behavior based on AIE property of the TPE unit. (c) 2019 Wiley Periodicals, Inc.
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