Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 7, Pages 4072-4085Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b00075
Keywords
-
Categories
Funding
- DST [YSS/2015/001552]
- RGNF
Ask authors/readers for more resources
A simple and efficient approach of C-S cross-coupling of a wide variety of (hetero)aryl thiols and (hetero)aryl halides under mild conditions, mostly at room temperature, catalyzed by well-defined singlet diradical Ni(II) catalysts bearing redox noninnocent ligands is reported. Taking advantage of ligand centered redox events, the high-energetic Ni(0)/Ni(II) or Ni(I)/Ni(III) redox steps were avoided in the catalytic cycle. The cooperative participation of both nickel and the coordinated ligands during oxidative addition/reductive elimination steps allowed us to perform the catalytic reactions under mild conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available