Journal
JOURNAL OF LUMINESCENCE
Volume 211, Issue -, Pages 363-374Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jlumin.2019.03.042
Keywords
beta-NaY1-xGdxF4(0 <= x <= 1.00); Solid solution microcrystals; Hydrothermal synthesis; Microstructures; Upconversion luminescence properties
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Funding
- National Science Foundation of China (NSFC) [51551202]
- Scientific Research Fund of Sichuan Provincial Education Department of Sichuan Province [16TD0007, 15ZA0363]
- Applied Basic Research Fund of Science & Technology Department of Sichuan Province [2015JY0274]
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Yb3+, Tm3+ co-doped beta-NaY1-xGdxF4 (0 <= x <= 1.00) microcrystals have been synthesized via a facile hydrothermal method. The influences of the concentration of Gd3+ on the morphology, grain size and upconversion luminescence of the as-synthesized co-doped beta-NaY1-xGdxF4 crystals have been investigated in detail. Powder Xray diffraction results confirm that the obtained beta-NaY1-xGdxF4 crystals are pure hexagonal solid solution. Scanning electron microscope results indicate that the morphology of the final obtained beta-NaY1-xGdxF4 crystals gradually changes from hexagonal prism to sphericity with increasing x, and the grain size monotonically decreases accordingly. The upconversion emission intensity of Tm3+ in the beta-NaY(1-x)GdxF(4) microcrystals increases initially and then decreases sharply with increasing x, giving the maximum at x = 0.04. The observed upconversion emission intensity located at 475 nm in co-doped beta-NaY0.74Gd0.04F4 microcrystal is 1.5 times greater than that of the co-doped beta-NaYF4 microcrystal. A superior upconversion host matrix of beta-NaY(1-x)GdxF(4) solid solution can be obtained at the feasible concentration of Gd3+ (0 < x <= 6%).
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