Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 366, Issue -, Pages 651-658Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2018.12.051
Keywords
N-Halamine; Phenolic; Mesoporous materials; Kinetics
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Funding
- Postgraduate Research & Practice Innovation Program of Jiangsu Provence [KYCX171444]
- scholarship for the Jiangnan University Scholarship Fund
- Fundamental Research Funds for the Central Universities [JUSRP51722B, JUSRP11806]
- Project of Jiangsu Science and Technological Innovation Team
- 111 Projects [B17021]
- national first-class discipline program of Light Industry Technology and Engineering [LITE2018-21]
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The reactions of a monomeric N-halamine, 1-chloro-5,5 dimethylhydantoin (MCDMH), and a mesoporous material-supported N-halamine (MMSNs) with phenol and p-cresol (two common contaminants in water) were investigated. MCDMH reacted rapidly with the phenolic compounds, and pH values had little effects on the reactions. On the contrary, MMSNs reacted with phenol and p-cresol only when the pH values were higher than 10. Phenol showed a lower reaction rate than p-cresol toward MMSNs. GC MS analysis suggested that MMSNs might react with the phenolic compounds through step-wise electrophilic chlorination reactions, and the main product was 2,4,6-trichlorophenol. The reaction kinetics were studied by following the disappearance of phenolic UV absorption bands, and the kinetic parameters were determined.
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