Double conductivity-improved porous Sn/Sn4P3@carbon nanocomposite as high performance anode in Lithium-ion batteries

Carbon encapsulated porous Sn/Sn4P3(Sn/Sn4P3@C) composite is conveniently prepared by one-step electrochemical dealloying of Sn80P20 alloy in mild conditions followed by growing one carbon layer. Controllable dealloying of the Sn80P20 alloy results in the formation of bicontinuous spongy Sn4P3 nanostructure with a part of residued metallic Sn atoms embedded in the porous skeleton. A uniform carbon layer is deposited on the nanoporous Sn/Sn4P3 to prevent the nanostructure's pulverizing and agglomerating during lithium ion insertion/extraction. Upon double conductivity modification from metallic Sn matrix and carbon layer, the as-made composite displays superior lithium-storage performances with much higher specific capacity as well as better cycling stability compared with pure porous Sn4P3. It offers a specific capacity of 837 mA h g(-1) after 100 cycles at a rate of 100 mA g(-1). Even after 700 cycles at the higher rate of 1000 mA g(-1), the specific capacity still maintains as high as 589 mA h g(-1). The Sn/Sn4P3@C material possesses promising application potential as an alternative anode in the lithium storage fields. (C) 2018 Elsevier Inc. All rights reserved.