Journal
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Volume 132, Issue -, Pages 978-986Publisher
ELSEVIER
DOI: 10.1016/j.ijbiomac.2019.03.088
Keywords
PVA/xylan composite films; Nano-ZnO; Nano-SiO2
Funding
- National Natural Science Foundation of China [201406080]
- Science and Technology Planning Project of Guangdong Province, China [2017A010103032]
- Fundamental Research Funds for the Central Universities of SCUT [2017ZD081]
- State Key Laboratory of Pulp and Paper Engineering [201533]
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The effects of nano-ZnO and nano-SiO2 on the properties of PVA/xylan composite films were investigated in this work. Results showed that nano-ZnO and nano-SiO2 could effectively improve the mechanical strength, moisture and oxygen barrier properties and surface hydrophobic property of the composite films. The results of FTIR and XRD indicated the interaction of hydrogen bonds between nanoparticles and PVA and xylan. When the contents of nano-ZnO and nano-SiO2 in the composite films were 3%, the tensile strength was increased to 20.4 MPa and 22.5 MPa, respectively, while water vapor permeability (3.14 and 3.03 x 10(-11) g.m(-1).s(-1).Pa-1) and oxygen permeability (5.28 and 5.003 cm(3).m(-2).24 h(-1).0.1 MPa-1) reached the minima. With the increase of nano-ZnO and nano-SiO2 dosage, the solubility of composite films was increased. When the contents of nano-ZnO and nano-SiO2 were 3% and 4%, respectively, the contact angles of the films was increased up to 101 degrees and 78 degrees. Besides, the composite films with nano-ZnO exhibited UV shielding performance, whereas the ones with nano-SiO2 had similar UV light-transparency to the pure PVA/xylan composite films. (C) 2019 Elsevier B.V. All rights reserved.
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