Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 101, Issue -, Pages 6-10Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2019.01.004
Keywords
Polyoxotantalate; Organic-inorganic hybrid; Magnetic property; {M6O19}-type POM
Categories
Funding
- National Natural Science Foundation of China [21671056]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [19HASTIT044]
- Basic and Frontier Technology Research Plan of Henan Province [152300410192]
- Henan University [yqpy20170010]
Ask authors/readers for more resources
Two neutral polyoxotantalates {[CuL](2)[Cu(L)(2)](2)[Ta6O19]}center dot nH(2)O have been synthesized by conventional reaction conditions, and characterized via different physical methods. Single-crystal X-ray analyses were carried out on {[CuL](2)[CuL2](2)[Ta6O19]}center dot 21H(2)O (L = 1,10-phen, denoted as 1) and the isostructural {[CuL](2)[CuL2](2)[Ta6O19)}center dot 20H(2)O (L' = 2,2'-bipy, denoted as 2). Both complexes comprise a Lindqvist [Ta6O59](8-) hexatantalate which acts as an octadentate ligand to coordinate two [CuL) units and two [CuL2) fragments through six bridging and two terminal oxygen atoms. In addition, the solid-state magnetic susceptibility of 1 and 2 are investigated briefly.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
