4.7 Article

A ZnII-Based Metal-Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone

Journal

INORGANIC CHEMISTRY
Volume 58, Issue 6, Pages 3578-3581

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b03316

Keywords

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Funding

  1. NNSF of China [21501077, 21761012, 21501078, 21561013, 21861018]
  2. China Postdoctoral Science Foundation [2016M592107]
  3. NSF of Jiangxi Province [20161ACB21013, 20171BCB23066, 20171BAB203005]
  4. Postdoctoral Daily Project of Jiangxi Province [2016RC31]
  5. Project of Jiangxi Provincial Department of Education [GJJ170497]
  6. Program for Cbngjiang Excellent Young Talents, JXUST

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A Zn-II-based metal organic framework (MOF) with a rare tcj topology has been solvothermally synthesized and displays relatively good thermal and chemical stabilities. Interestingly, the MOF can sensitively and selectively sense acetylacetone (acac) via a fluorescence enhancement effect with a detection limit of 0.10 ppm and good reusability, which demonstrates the first example of a MOF-based turn -on fluorescent sensor for acac.

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