Journal
INORGANIC CHEMISTRY
Volume 58, Issue 4, Pages 2686-2694Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b03294
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Funding
- SERB, India [SB/FT/CS -185/2012]
- DST, Government of India [BT/01/CEIB/11/V/13]
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A novel mixed ligand one-dimensional coordination polymer (1D CP), {[Cd-2(adc)(2)(4-nvp)(6)]-(MeOH)center dot(H2O)}(n) (1; H(2)adc = 9,10-anthracenedicarboxylic acid, and 4-nvp = 4-(1-naphthylvinyl)pyridine), has been synthesized and structurally characterized by single crystal X-ray crystallography. The ID polymer undergoes supramolecular aggregation via hydrogen bonding, C-H center dot center dot center dot pi., and pi center dot center dot center dot pi interactions. Interestingly, compound 1 shows increasing conductivity upon irradiation of light. Therefore, it has the potential to be used in optoelectronic devices. Moreover, the supramolecular assembly of 1 specifically detects Cr3+ cation in the presence of other competitive analytes. Most importantly, compound 1 exhibits fascinating turn-on Cr3+ sensing, which seems to be an ornament in the field of sensing application.
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