4.6 Article

Fabrication of Flexible and Superhydrophobic Melamine Sponge with Aligned Copper Nanoparticle Coating for Self-Cleaning and Dual Thermal Management Properties

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 58, Issue 12, Pages 4844-4852

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b00041

Keywords

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Funding

  1. National Natural Science Foundation of China [21706100, 61705101, 21878132]
  2. Natural Science Foundation of Jiangsu Province [BK20161362, BK20160491, BK20160500]
  3. China Postdoctoral Science Foundation [2018T110452, 2017M621649]
  4. China Postdoctoral Science Foundation of Jiangsu Province [1701067C, 1701073C]
  5. Youth Talent Cultivation Program of Jiangsu University, Key Research and Development Program of Jiangxi Province [20171BBH80008]
  6. Society Development Fund of Zhenjiang City [SH201 80 09, SH2018011, SSH20180140124]
  7. 333 High-Level Personnel Training Project of Jiangsu Province [BRA2016142]

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In this work, a three-dimensional (3D) flexible copper coated melamine sponge (Cu-MES) with super-hydrophobic properties capable of active heating and infrared insulation is fabricated via deposition of copper nanoparticles on the MES surfaces for personal thermal management applications. The results showed that the Cu nanoparticles were tightly anchored on the surface of the melamine sponge, forming a low infrared emissivity coating, resulting in high thermal insulation properties of the multifunctional Cu-MES. The promising electrical conductivity grants the superior Joule heating for extra warmth of 40 degrees C using a low supply voltage around 7 V. Besides, obtained Cu-MES material shows a self-cleaning property with a stable water contact angle of 157.5 degrees and a sliding angle of 15 degrees. These promising results including low infrared emissivity for high thermal insulation and high conductivity for heat collection make the Cu-MES promising candidates for applications in personal thermal management, energy regulation, and other facilities.

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