Influence of Electric Parameters on Hydroxyl Radical Production by Positive Pulsed Discharge Inside of a Bubble in Water

The influence of the electric parameters, applied voltage, and pulse repetition rate on the energy efficiency for hydroxyl radical production from pulsed discharge inside of a bubble is investigated in this paper, as a possible application for waste water treatment. To evaluate the energy efficiency, indigo carmine, a common dye, is used as a chemical probe of hydroxyl radicals. Argon is injected into water through a vertically positioned glass tube, into which high-voltage wire electrode is placed to generate plasmas at low applied voltage. The energy efficiency increases with the decreasing pulse repetition rate and output voltage with the same indigo carmine concentration. The results show that the energy efficiency for the hydroxyl radical production increases with the decreasing amount of energy input into the solution per unit time because of the decrease in the recombination reaction of the hydroxyl radicals in the solution. The impedance between the electrodes decreases with the increasing output voltage, which increases the ohmic losses in the solution but does not contribute to the production of hydroxyl radicals.