Journal
FRACTALS-COMPLEX GEOMETRY PATTERNS AND SCALING IN NATURE AND SOCIETY
Volume 27, Issue 1, Pages -Publisher
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S0218348X19400140
Keywords
Fractal Characteristics; Shale Gas; Organic Pore; Self-Similarity; Methane Adsorption
Funding
- National Natural Science Foundation of China [41472135, 41702167, 41772141]
- National Postdoctoral Program for Innovative Talents [BX201700282]
- China Postdoctoral Science Foundation [2017M621870]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Pore structure in shale controls the gas storage mechanism and gas transport behaviors. Since nanoscale pores in shale matrix have fractal characteristics, fractal theory can be used to study its structure. In addition, fractal method has its own advantages to investigate nanopores in shale, especially for the heterogeneity and irregularity of nanopores in shale. In this work, fractal features of nanoscale pores and the implication on methane adsorption capacity of shale were investigated by employing low pressure nitrogen adsorption, scanning electron microscopy (SEM), and methane adsorption experiments. Frenkel-Halsey-Hill (FHH) model was also used to calculate the fractal parameters of nanoscale pores in shale. The results showed that nanoscale pores in 12 shale samples have obvious fractal features. All the fractal curves of these shale samples can be divided into two segments, which are cut off by P/P-0 = 0.5, and the fractal dimensions of these two segments vary from 2.48 to 2.92 (D1) and 2.42 to 2.80 (D2), respectively. Based on SEM images, it is found that self-similarity of organic pore systems in shales refers to two aspects. One is that relatively large-scale and small-scale pores have similar formation properties and types, which are of elliptical shape with rough surface. The other is that some small-scale pores are formed by rough surface of relatively large pores. The results also demonstrate that methane adsorption capacity of shale samples increase with increasing total organic carbon (TOC) contents. This is mainly because organic matter is rich in pores and has relatively large fractal dimension values. Larger fractal dimensions indicate rougher pore surfaces and could form more small-scale organic pores. These organic pores would provide more space for methane adsorption.
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