Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 14, Pages 2437-2447Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801833
Keywords
Carbon dioxide fixation; Reduction; Synthetic methods; Transition metal catalysis; Nucleophiles
Categories
Funding
- National Program on Key Research Project of China [2016YFA0602900]
- National Natural Science Foundation of China [21672119]
- Natural Science Foundation of Tianjin Science and Technology Commission [16JCZDJC39900]
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Reductive functionalization of CO2 combining both the formation of the new bonds and CO2 reduction in the presence of reductant, such as molecular hydrogen, hydrosilane, or hydroborane has become increasingly attractive, which enlarges the spectra of compounds directly available from CO2 thus provides fresh idea for CO2 chemistry. This microreview briefly summarizes recent advances in new bond construction using CO2 as formyl, methylene, and methyl source with transition-metal catalyst, which are divided into sections according to C-N, C-C, and C-O bonds formation in the presence of nitrogen-, carbon-, and oxygen-nucleophiles respectively. The challenges and opportunities with future trends of the reductive functionalization of CO2 are discussed as well.
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