Journal
COORDINATION CHEMISTRY REVIEWS
Volume 382, Issue -, Pages 32-56Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.12.003
Keywords
Zintl ion; Group 14 elements; Cage compounds; Chemical bonding; Intermetalloid clusters
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Funding
- National Natural Science Foundation of China [21722106, 21571171, 21871246]
- Jilin Province innovative research program [20160519004JH]
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The solution chemistry of Group 14 Zintl-type clusters is of growing interest as a result of their potential to be used as molecular building blocks for the construction of nanoscale architectures. Here we review the synthesis of homoatomic and heteroatomic Group 14 Zintl anions, with particular emphasis on their direct coordination to organic species, main-group elements and transition metal fragments. (C) 2018 Elsevier B.V. All rights reserved.
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