Journal
COMBUSTION AND FLAME
Volume 201, Issue -, Pages 148-159Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.combustflame.2018.12.023
Keywords
Soot oxidation; Reduced mechanisms; Surface reactivity; Particle dynamics
Ask authors/readers for more resources
New formulation is introduced to model surface oxidation of soot particles. In the new development, the surface is represented by an arbitrary number of reactive sites and their physically-founded transformations. The latter are combined and integrated with gas-phase and particle-dynamics models. The surface reaction model defines two state properties and establishes a structural relationship between them that guides evolution of the surface. This new model form for the surface-chemistry led to close reproduction of shock-initiated oxidation of soot: CO profiles in two experiments performed at substantially different temperatures, 1990 and 2780 K, as well as CO production rates over a wide range of temperatures, 1652-3130K, all without employing the parameter-a empiricism of the previous model formulation. (C) 2018 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available