Journal
CHEMSUSCHEM
Volume 12, Issue 13, Pages 3018-3022Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201900439
Keywords
alkene; bismuth vanadate; C-C bond cleavage; molecular oxygen; photocatalysis
Funding
- National Research Foundation of Korea [2012M3A7B4049657, 2014-011165, 2017R1E1A1A01074224, 2017R1A2B2004082] Funding Source: Medline
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BiVO4 crystals synthesized by an ultrasonic-assisted method (Sono-BiVO4) showed improved efficiency as a heterogeneous photocatalyst under visible-light irradiation. Sono-BiVO4 was successfully used for the C-C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono-BiVO4 under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono-BiVO4 could be easily separated from the reaction mixture and reused.
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