Journal
CHEMISTRY LETTERS
Volume 48, Issue 2, Pages 133-136Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180888
Keywords
Conjugated macrocyclic molecule; Quinoline; Isocyanide-acetylene cyclization reaction
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A conjugated macrocyclic molecule incorporating two m-diethynylene-phenylene-bridged quinoline moieties was synthesized via isocyanide-acetylene cyclization and Pd/Cu-catalyzed Sonogashira cross-coupling reactions. X-ray crystal analysis and DFT calculation revealed that the new macrocyclic molecule has a rigid parallelogram structure. The photophysical and electrochemical properties were studied by several spectral analyses, and were rationalized by DFT calculations.
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