Journal
CHEMICAL RECORD
Volume 19, Issue 10, Pages 2095-2104Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201800194
Keywords
desymmetrization; atropisomers; stereogenic axis; organocatalysis; vinylogy; nucleophilic substitution; kinetic resolution
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Funding
- University of Bologna
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The enantioselective synthesis of atropisomers is an emerging field, that in recent years reached fundamental results and put the bases for innovative applications. Organocatalysis is playing a central role in the realization of original synthesis for novel atropisomeric scaffolds.([1]) In this short review, we would like to highlight the results obtained by our group and others in the field of axially enantioselective desymmetrization reactions using organocatalysis as main strategy.
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