Journal
CHEMICAL ENGINEERING JOURNAL
Volume 359, Issue -, Pages 882-893Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.11.101
Keywords
SiC whiskers; Biomass-derived carbon; Polypyrrole; Electromagnetic wave absorption
Categories
Funding
- China National Funds for Distinguished Young Scientists [51525201]
- Innovative Research Group of National Natural Science Foundation of China [91216301, 11421091, 51202048, 11402252, 51372047]
- State Key Laboratory of Advanced Welding and Joining [17-M-07]
- Fundamental Research Funds for the Central Universities [HIT.BRETIII.201506]
- National Key Laboratory of Science and Technology on Advanced Composites in Special Environments [KL.PYJH.2016.001]
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To achieve high-performance electromagnetic (EM) wave absorbing performances, biomass-derived carbon (BDC) and conductive polymer polypyrrole (PPy) were incorporated on SiC whiskers (SiCw) by hydrothermal-carbonization-polymerization. Modulation of the mass ratio of SiCw/glucose (SiCw/Glu) can effectively improve the permittivity of SiCw-BDC composites in a large scale, leading to the enhanced EM wave absorption property. Compared with the wave-transparent of pristine SiCw, the SiCw-BDC composite with the SiCw/Glu mass ratio of 0.5 (S-0.5) shows a strong EM wave absorption capacity with a minimum reflection loss (RLmin) value of - 24.6 dB at 13.2 GHz, and its effective bandwidth is up to 6.8 (11.2-18.0) GHz, which could achieve effective absorption of EM waves in entire Ku-band with a wide thickness range of 2.28-2.49 mm. Adjusting the polymerization time of PPy could efficiently control the EM wave absorbing performance of SiCw-BDC/PPy heterostructures, and the sample SiCw-BDC/PPy heterostructure with 1.0 h polymerization time exhibits the optimal microwave absorption property, with a RLmin value of -52.4 dB at 11.4 GHz and effective bandwidth of 8.1 (9.0-17.1) GHz. The electronic dipole polarization, relaxation polarization loss and interfacial polarization with the matched characteristic impedance and improved loss ability within SiCw-BDC/PPy heterostructures are major determining factors of excellent EM wave absorption properties, and the SiCw-BDC/PPy heterostructures in this study are as a promising candidate for next-generation high-performance EM wave absorber for practical applications.
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