Journal
CHEMICAL ENGINEERING JOURNAL
Volume 357, Issue -, Pages 447-457Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.09.150
Keywords
Mild steel; Zn(II) Schiff base complexes; X-ray diffraction; EIS; Polarization; Acid inhibition; Antibacterial and ant proliferative activity
Categories
Ask authors/readers for more resources
Four novel biologically significant Zn (II) Schiff base complexes ([Zn(L-1)(2)](ClO4)(2) (1), [Zn(mu-fumarate)(L1)](n) (2), [ZnL1(N-3)(2)] (3) and [ZnL2(N-3)(2)] (4) were synthesized from two ligands L-1 [N-1,N-1-dimethyl-N-2-(1-(pyridine-2-yl)ethylidene)ethane-1,2-diamine]and L-2 [N-1,N-1-diethyl-N-2-(1-(pyridine-2-yl)ethylidene)ethane-1,2-diamine]. Detailed electrochemical polarization and impedance studies prove that corrosion inhibition activity of newly synthesized zinc complexes in 15% HCl on mild steel gets enhanced significantly due to the incorporation of psudo-halide azide as co-ligand. Different microscopic images (FE-SEM and AFM) depicted that metal surface is protected by Zn(II) complexes. Antibacterial activity of these Zn (II) azido Schiff base complexes against Grampositive Staphylococcus aureus was studied and reported. Further, antiproliferative activities of these azido complexes were studied against breast cancer cell line MCF 7.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available