Journal
CHEMICAL ENGINEERING JOURNAL
Volume 357, Issue -, Pages 395-403Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.09.158
Keywords
Catalytic propane oxidation; Pt/LaCoO3; Co3+/Co2+ redox cycle; Interaction; Mars-van Krevelen mechanism
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Funding
- National Natural Science Foundation of China [21875037, 21407025]
- National Science Foundation of Fujian Province [2016J01047]
- New Century Talent Project of Fujian Province
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In the present work, 0.29 wt% Pt/LaCoO3 nanorods with high N dispersion were prepared by using high surface area of electrospun LaCoO3 nanorods (31 m(2)/g) as the support, and the physicochemical properties are correlated with the propane oxidation activities. It is demonstrated that sequential thermal annealing in He, O-2, and H-2 can achieve well N dispersion and good interaction between metallic N and LaCoO3 nanorods. The latter leads to a good reducibility and high oxygen mobility, resulting in a rapid redox cycle of Co3+/Co2+. It mainly contributes to the good propane oxidation activity following the Mars-van Krevelen mechanism for N/LaCoO3-He + O-2 + H-2. Meanwhile, it exhibits good thermal stability and water resistant. Additionally, a unique circulation in situ FTIR technology was developed to detect the intermediate species for the weak interaction of propane with Pt/LaCoO3.
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