Journal
CHEMCATCHEM
Volume 11, Issue 21, Pages 5292-5295Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201900387
Keywords
alkenylation; C-H activation; manganese; amidines; stereoselectivity
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The first ortho-alkenylation of aromatic amidines with alkynes was realized by earth-abundant manganese catalysis through C-H activation. A catalytic amount of PhMgBr was found essential for improved efficiency of this transformation. Wide tolerance of functional groups and excellent E/Z selectivity highlighted the current protocol.
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