Journal
CHEMCATCHEM
Volume 11, Issue 9, Pages 2350-2354Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201900438
Keywords
decarboxylation; electrochemistry; external chemical oxidant-free; metal-free; trifluoromethylation
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Funding
- National Natural Science Foundation of China [21672074, 21372089]
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A new method for the synthesis of vinyl trifluoromethyl compounds from , -unsaturated carboxylic acids and CF3SO2Na has been developed. This electrochemical decarboxylative trifluoro-methylation was found to be highly stereoselective and afforded products in good yields with wide substrate scope under metal-free and external chemical oxidant-free conditions.
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