4.8 Article

Cicada slough-derived heteroatom incorporated porous carbon for supercapacitor: Ultra-high gravimetric capacitance

Journal

CARBON
Volume 143, Issue -, Pages 309-317

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2018.11.011

Keywords

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Funding

  1. National Key Research and Development Program of China [2016YFA0501602]
  2. National Natural Science Foundation of China [61871113, 51420105003]

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Heteroatom incorporated porous carbon from cicada slough, has been synthesized through a simple activation process. The cicada slough-based porous carbon has high potency of naturally-derived heteroatom functionalities (similar to 12.06% atomic ratio of nitrogen, oxygen, sulfur, and phosphorus), welldeveloped microporosity and high specific surface area (1676m(2) g(-1)). Supercapacitor involves the asobtained carbon as electrode material showing ultra-high specific capacitance of 355 F g(-1) at the current density of 1 A g(-1) and excellent rate capability of 284 F g(-1) at 30 A g(-1). The retention of specific capacitance of the working electrode remains over 90% after 3000 cycles at 10 A g(-1). Single electrode in the symmetric-two-electrode test also delivers high specific capacitance of 274 F g(-1) with the energy density up to similar to 9.0Wh kg(-1) in aqueous electrolyte. These outstanding results suggest the biomass derived porous carbon possessing the potential for the fabrication of high performance supercapacitors. (C) 2018 Elsevier Ltd. All rights reserved.

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