Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 15, Issue -, Pages 521-534Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.15.46
Keywords
isocyanides; multicomponent reactions; reaction discovery; selectivity
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Funding
- Ministerio de Economia y Competitividad-Spain (MINECO) [CTQ2015-67870-P]
- Generalitat de Catalunya [2017 SGR 1439]
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Multiple multicomponent reactions reach an unparalleled level of connectivity, leading to highly complex adducts. Usually, only one type of transformation involving the same set of reactants takes place. However, in some occasions this is not the case. Selectivity issues then arise, and different scenarios are analyzed. The structural pattern of the reactants, the reaction design and the experimental conditions are the critical factors dictating selectivity in these processes.
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