4.5 Article

Significant THz-wave absorption property in mixed δ- and α-FAPbI3 hybrid perovskite flexible thin film formed by sequential vacuum evaporation

Journal

APPLIED PHYSICS EXPRESS
Volume 12, Issue 5, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.7567/1882-0786/ab0eec

Keywords

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Funding

  1. JSPS KAKENHI (Japan) [17K05033]
  2. Basic Science Research Program through the National Research Foundation of Korea [NRF-2015R1C1A2A01054543, NRF-2018R1D1A1B07042814, NRF-2018R1D1A1B07047762]
  3. Ministry of Education of the Republic of Korea
  4. Australian Research Council through its DECRA
  5. Programs for Professor of Special Appointment and Distinguished Visiting Professor (Eastern Scholar) at the Shanghai Institutions of Higher Learning
  6. Australian Research Council through its DP
  7. Grants-in-Aid for Scientific Research [17K05033] Funding Source: KAKEN

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The flexible and mixed delta- and alpha-formamidinium lead iodide (FAPbI(3)) hybrid perovskite thin films fabricated by the sequential vacuum evaporation method (SVE) were studied using the THz-wave absorption property. The formed FAPbI(3) using SVE showed the typical delta-phase. After annealing for 10 min, we confirmed a mixed state with delta- and alpha-phases and observed THz-wave absorption at 1.62 THz with 40% absorptance. In the C 1s core-level spectra, we found two different chemical states originated from delta- and alpha-FAPbI(3). The origin of the THz-wave absorption property is assumed from a significant Pb-I vibration mode from the mixed phases in FAPbI(3). (C) 2019 The Japan Society of Applied Physics

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