Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 33, Issue 4, Pages -Publisher
WILEY
DOI: 10.1002/aoc.4842
Keywords
cross-coupling; graphene oxide; heterogeneous nanocatalyst; palladium-catalyzed; terpyridine-based ligands
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Funding
- Razi University Research Council
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The palladium nanoparticles were successfully stabilized with an average diameter of 6-7 nm through the coordination of palladium and terpyridine-based ligands grafted on graphene oxide surface. The graphene oxide supported palladium nanoparticles were thoroughly characterized and applied as an efficient heterogeneous catalyst in carbon-carbon (Suzuki-Miyaura, Mizoroki-Heck coupling reactions) and carbon-heteroatom (C-N and C-O) bond-forming reactions. The catalyst was simply recycled from the reaction mixture and was reused consecutive four times with small drop in catalytic activity.
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