Journal
APPLIED MAGNETIC RESONANCE
Volume 50, Issue 7, Pages 895-902Publisher
SPRINGER WIEN
DOI: 10.1007/s00723-019-01115-x
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Funding
- project iNAPO by the Hessen State Ministry of Higher Education, Research and the Arts
- Deutsche Forschungsgemeinschaft [BE 1824/12-1, BU-911-22-1]
- Polish National Science Centre [UMO-2016/21/B/ST4/02162]
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A number of Ir-N-heterocyclic carbene (Ir-NHC) complexes with asymmetric N-heterocyclic carbene (NHC) ligands have been prepared and examined for signal amplification by reversible exchange (SABRE). Pyridine was chosen as model compound for hyperpolarization experiments. This substrate was examined in a solvent mixture using several Ir-NHC complexes, which differ in their NHC ligands. The SABRE polarization was created at 6mT and the H-1 nuclear magnetic resonancesignals were detected at 7T. We show that asymmetric NHC ligands, because of their favorable chemistry, can adapt the SABREactive complexes to different chemical scenarios.
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