Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 21, Pages 7097-7101Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902607
Keywords
alkenes; fluorine; hydrofluorination; iron; silanes
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Funding
- National Key Research and Development Program of China [2018YFD0200100, 2017YFD0200505]
- National Natural Science Foundation of China [21672107, 21871145]
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An iron-catalyzed hydrofluorination of unactivated alkenes has been developed. The use of a multidentate ligand and the fluorination reagent N-fluorobenzenesulfonimide (NFSI) proved to be critical for this reaction, which afforded various fluorinated compounds in up to 94% yield.
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