Journal
AICHE JOURNAL
Volume 65, Issue 8, Pages -Publisher
WILEY
DOI: 10.1002/aic.16606
Keywords
extraction; ionic liquids; lithium; trialkylphosphine oxide
Categories
Funding
- National Natural Science Foundation of China [21706257]
- Key Program of National Natural Science Foundation of China [91434203]
- Fund of State Key Laboratory of Multiphase Complex Systems [MPCS-2017-A-08]
- Shanxi Province Coal Based Low-carbon Technology [MC2016-05]
- Fujian Institute of Innovation, Chinese Academy of Sciences [FJCXY18040101]
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The solvent extraction of Li+ by Cyanex 923 was investigated upon the addition of different imidazolium-based ionic liquids (ILs). The results showed 1-hydroxylethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([HOEmim][NTf2]) can improve the extraction of Li+ most effectively. The fundamental mechanism is that [HOEmim][NTf2] can remarkably enhance the coordination ability of Cyanex 923 to Li+ to form more stable and hydrophobic ion-pair species [Li(Cyanex 923)(n)][NTf2] (n(max) = 3) resulting from the electrostatic interaction and typical hydrogen bonding of IL, and thus facilitating the transfer of Li+ into organic phase. This work has revealed the transfer mechanism of Li+ in a solvent extraction system comprising of IL and neural ligand. The knowledge of the coordination environment of Li+ in the presence of IL also gives us a new insight into the separation of Li-6/Li-7. The disadvantage of this process is the loss of IL. However, this study provides guidance for the design of better IL-based systems for the separation of metal ions.
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