Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 29, Issue 17, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201807191
Keywords
adsorption; elemental mercury; flue gas; selenide; zeolitic imidazolate framework-8
Categories
Funding
- National Natural Science Foundation of China [51776227]
- Natural Science Foundation of Hunan Province, China [2018JJ1039, 2018JJ3675]
- Research Council of Hong Kong [17257616, C7044-14G, T21-771/16R]
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A key challenge in elemental mercury (Hg-0) decontamination from flue gas lies in the design of a sorbent with abundant reactive adsorption sites that exhibit high affinity toward Hg-0 to simultaneously achieve rapid capture and large capacity. Herein, zeolitic imidazolate framework-8 (ZIF-8) supported copper selenide (CuSe) nanocomposites are synthesized by a newly designed two-step surfactant-assisted method. The as-prepared CuSe/ZIF-8 with CuSe to ZIF-8 mass ratio of 80% (0.8NC-ZIF) exhibits unparalleled performance toward Hg-0 adsorption with equilibrium capacity and average rate reaching 309.8 mg g(-1) and 105.3 mu g g(-1) min(-1), respectively, surpassing all reported metal sulfides and traditional activated-carbon-based sorbents. The impressive performance of 0.8NC-ZIF for Hg-0 immobilization is primarily attributed to the adequate exposure of the Se-terminated sites with high affinity toward Hg-0 resulted from the layered structure of CuSe. The adsorbed mercury selenide exhibits even higher stability than the most stable natural mercury ore-that is, mercury sulfide hence minimizing its environmental impact when the CuSe/ZIF-8 sorbent is dumped. This work provides a new mindset for future design of sorbents for efficient Hg-0 capture from industrial flue gas. The results also justify the candidature of CuSe/ZIF to be applicable for mercury pollution remediation in real-world conditions.
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