4.8 Article

Measurements of the Thermal Resistivity of InAlAs, InGaAs, and InAlAs/InGaAs Superlattices

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 12, Pages 11970-11975

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b17268

Keywords

thermal conductivity; thermal resistivity; superlattice; InAlAs; InGaAs; quantum cascade laser

Funding

  1. United States Department of Energy (DOE), Basic Energy Sciences [DE-FG02-03ER46028]
  2. DOE award [DE-SC0008712]
  3. NSF [1702561]
  4. AFOSR [FA9550-18-1-0340]
  5. NSF through the UW-Madison MRSEC [DMR-1720415]
  6. [N68335-11-C-0432]
  7. [N68335-15-C-0073]
  8. [W911NF-16-C-0116]
  9. Directorate For Engineering
  10. Div Of Chem, Bioeng, Env, & Transp Sys [1702561] Funding Source: National Science Foundation
  11. U.S. Department of Energy (DOE) [DE-SC0008712, DE-FG02-03ER46028] Funding Source: U.S. Department of Energy (DOE)

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Thermal management efforts in nanoscale devices must consider both the thermal properties of the constituent materials and the interfaces connecting them. It is currently unclear whether alloy/alloy semiconductor super-lattices such as InAlAs/InGaAs have lower thermal conductivities than their constituent alloys. We report measurements of the crossplane thermal resistivity of InAlAs/InGaAs superlattices at room temperature, showing that the super-lattice resistivities are larger by a factor of 1.2-1.6 than that of the constituent bulk materials, depending on the strain state and composition. We show that the additional resistance present in these superlattices can be tuned by a factor of 2.5 by altering the lattice mismatch and thereby the phonon-mode mismatch at the interfaces, a principle that is commonly assumed for superlattices but has not been experimentally verified without adding new elements to the layers. We find that the additional resistance in superlattices does not increase significantly when the layer thickness is decreased from 4 to 2 nm. We also report measurements of 250-1000 nm thick films of undoped InGaAs and InAlAs lattice-matched to InP substrates, for there is no published thermal conductivity value for the latter, and we find it to be 2.24 +/- 0.09 at 22 degrees C, which is similar to 2.7 times smaller than the widely used estimates.

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